• ISSN 0495-5331  CN 11-2043/P  双月刊
  • 主管单位:中国钢铁工业协会
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                      中国地质学会
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金属矿山尾矿库区土壤重金属元素释放迁移规律研究
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中国地质调查局项目(编号:1212011120764)、山西省自然科学基金项目(编号:202403021222498)和山西省级公益性地勘项目(编号:2024-53)联合资助


The Release and Migration Regularity of Heavy Metal Elements in Soil of Tailings Pond Area of Metal Mines
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    摘要:

    为揭示尾矿库周边土壤中重金属的赋存形态、释放机制及迁移路径,本文提出金属矿山尾矿库区土壤重金属元素释放迁移规律研究方法。该方法以某大型铜矿为研究区,将尾矿库划分为 50 m × 50 m 50m×50m 网格,在每个网格中心及垂直剖面不同位置设采样点,采集表层 20 c m 20cm 土壤样本,经预处理后,利用等离子体原子发射光谱仪测定重金属含量。同时设计淋滤试验装置,以不同 p H pH 值 (4.5、6.0、7.5) 和淋滤强度 (55 mm/h、110 mm/h、180 mm/h) 的淋滤液对土柱进行淋滤,在土壤不同深度和不同淋滤条件下,使用原子吸收分光光度计测定淋出液中 P b Pb 、Zn的释放浓度,分析土壤重金属元素释放迁移规律。试验表明:土壤粒径影响重金属迁移,细颗粒吸附能力强,限制重金属迁移,粗颗粒利于迁移;酸性条件 ( p H = 4.5 pH=4.5 ) 下, P b Pb 、Zn释放浓度更高,更易从土柱上层向下层迁移;淋滤强度增大, P b Pb 、Zn在各出水口释放浓度升高,迁移量增加;垂向上,随土壤深度增加,各土柱 P b Pb 、Zn释放浓度呈下降趋势,酸性条件加速重金属由上层向下层迁移, p H pH 升高,重金属释放量减少,残留浓度相对较高。本研究阐明了尾矿库区土壤重金属在不同环境条件下的释放迁移行为与关键驱动因素,研究成果对科学评估尾矿库周边土壤污染风险、预测重金属长期迁移趋势具有重要理论价值,并为制定针对性的尾矿库区域生态修复与污染防控策略提供了可靠的数据支撑和科学依据。

    Abstract:

    To reveal the occurrence forms, release mechanisms, and migration pathways of heavy metals in the soil surrounding tailings ponds, this work proposes a research method for the release and migration regularity of heavy metal elements in soil of tailings ponds area of metal mine. This method takes a large copper mine as the study area, divides the tailings pond into 50 m × 50 m 50m×50m grids. Sampling points were set at the center of each grid and at different positions along vertical sections. Surface soil samples from the top 20 c m 20cm were collected, pretreated, and analyzed for heavy metal content using an inductively coupled plasma atomic emission spectrometer. Simultaneously, a leaching test apparatus was designed to leach the soil column with leachate of different pH values (4.5, 6.0, 7.5) and leaching intensities (55 mm/h, 110 mm/h, 180 mm/h). The release concentrations of Pb and Zn in the leachate were measured using an atomic absorption spectrophotometer at different depths of soil and under different leaching conditions to analyze the release and migration patterns of heavy metal elements in the soil. Experiments have shown that soil particle size affects the migration of heavy metals. Fine particles have strong adsorption capacity, limiting the migration of heavy metals, while coarse particles facilitate migration. Under acidic conditions (pH 4.5), the release concentration of Pb and Zn is higher, making it easier to migrate from the upper layer to the lower layer of the soil column. As the leaching intensity increases, the release concentration of Pb and Zn at each outlet increases, and the migration amount increases. Vertically, with increasing soil depth, the release concentrations of Pb and Zn in each soil column show a decreasing trend. Acidic conditions accelerate the migration of heavy metals from the upper layer to the lower layer, increase pH, reduce heavy metal release, and result in relatively high residual concentrations. This study clarifies the release and migration behaviors of heavy metals in the soil of tailings ponds under different environmental conditions and the key driving factors. The research results have significant theoretical value for scientifically assessing the soil pollution risks around tailings ponds and predicting the long-term migration trends of heavy metals. They also provide reliable data support and scientific basis for formulating targeted ecological restoration and pollution prevention and control strategies in the tailings pond area.

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郑仲,李猛兴,张尚清.金属矿山尾矿库区土壤重金属元素释放迁移规律研究[J].地质与勘探,2026,62(1):134-142

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  • 收稿日期:2025-04-27
  • 最后修改日期:2025-06-08
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  • 在线发布日期: 2026-02-04
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