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重庆秀山大塘坡组锰矿床地球化学特征及成因分析
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国家自然科学基金项目(编号:U1812402、41890840)和中国科学院创新交叉团队CASIIT(编号:JCTD-2019-17)联合资助


Geochemical Characteristics and Genesis of the Datangpo Formation Manganese Deposits in the Xiushan Area, Chongqing
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    摘要:

    重庆秀山小茶园锰矿床和笔架山锰矿床位于渝湘黔锰矿带,产出于北东-南西向次级地堑盆地中心,矿体赋存于南华系上统大塘坡组第一段黑色页岩内,被称为“大塘坡式”锰矿。本文以小茶园锰矿床和笔架山锰矿床为研究对象,通过扫描电镜-能谱仪(SEM-EDS)、元素地球化学、有机碳含量(TOC)和铊的形态分析,探讨大塘坡组锰矿床地球化学特征及其成因。研究结果显示,小茶园锰矿床与笔架山锰矿床具有相似的地球化学特征,锰矿石中MnO、CaO、MgO、FeO和P2O含量相对较高,Al2O3、K2O、Na2O和TiO2含量相对较低,Al标准化后微量元素Co、Cu、Ga、Mo、Sr、Zn、Ni等均有不同程度富集。锰矿床具有热水沉积特征,且受热液活动的影响,菱锰矿石面扫描图显示元素Mn与Eu具有明显的正相关性,进一步指示锰质来源于热液体系。锰矿床沉积时水体为缺氧环境,利于有机质保存并厌氧氧化释放出大量的CO2,海水中的CO32-浓度达到饱和并与沉积盆地中的高Mn2+直接沉淀为MnCO3,该发现为锰矿床成因分析提供了新的依据。

    Abstract:

    The Xiaochayuan and Bijiashan manganese deposits in the Xiushan area, Chongqing, are located within the Chongqing-Hunan-Guizhou manganese ore belt. They occur in the center of a NE-SW trending secondary graben basin, with ore bodies hosted in black shales of the first member of the Datangpo Formation in the upper Nanhua System, collectively referred to as the "Datangpo-type" manganese deposits. This study investigates the geochemical characteristics and genesis of the Datangpo Formation manganese deposits by focusing on the Xiaochayuan and Bijiashan deposits. Analytical methods includes scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), elemental geochemistry, total organic carbon (TOC) content, and thallium speciation. The results indicate that the Xiaochayuan and Bijiashan deposits share comparable geochemical characteristics. In manganese ores, the concentrations of MnO, CaO, MgO, FeO, and P2O5 are relatively high, while those of Al2O3, K2O, Na2O and TiO2 are relatively low. After Al normalization, trace elements such as Co, Cu, Ga, Mo, Sr, Zn and Ni exhibit varying degrees of enrichment. The manganese deposits display features indicative of hydrothermal sedimentation and are influenced by hydrothermal activities. The scanning electron microscopy images of rhodochrosite ore surfaces reveal a significant positive correlation between the elements Mn and Eu, further indicating that the manganese originates from a hydrothermal system. During the deposition of manganese deposits, the water environment was anoxic, which was conducive to the preservation and evolution of organic matter and the release of large amounts of CO2 through anaerobic oxidation. The concentration of CO32- in seawater reached saturation, leading to direct precipitation of MnCO3 with enriched Mn2+ ions in the sedimentary basin. The discovery provides new evidence for the analysis of the genesis of manganese deposits.

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田欢欢,樊海峰,何明勤,梁坤萍,刘华德,蒋宗旭.重庆秀山大塘坡组锰矿床地球化学特征及成因分析[J].地质与勘探,2026,62(1):42-57

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  • 收稿日期:2024-04-22
  • 最后修改日期:2024-12-24
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  • 在线发布日期: 2026-02-04
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